Hydrochemical Studies

 

 

Ground Water Quality

 

Regional Chemical Laboratory

 

Ground Water Quality Monitoring

 

Ground Water Contamination

 

Water Quality and Human Health

 

Water Quality Standards

 

Ground Water Pollution Studies

 

 

 

 

 

 

Ground Water Quality

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The term "Ground Water Quality" covers a widespread meaning and is referred by an individual depending on the suitability of ground water for the intended use. Ground water quality is indicated by the amount of dissolved or suspended inorganic or organic materials in it through which it acquires physical and chemical characteristics. Under natural condition, the composition of ground water depends on the composition of rainwater, soil strata and aquifer materials and changes with time and space. With the rapid development in urbanization, industrialization, agricultural and mining activities, the ground water contamination with hazardous waste and wastewater is becoming a common phenomenon. The water quality and human health are closely related. The use of such contaminated water for drinking purpose may cause an adverse impact on human health. The determination of the physical, chemical and bacteriological quality of ground water is becoming essential to evaluate the water quality for different purposes as per the water quality standards laid down by different agencies.

 

 

 

 

 

The CGWB, CR, Nagpur is carrying out the ground water quality monitoring in Maharashtra State and the Union Territory of Dadra and Nagar Haveli for the past three decades to assess the trend in the ground water quality and its suitability for the different purposes. The required facility for the analysis of ground water samples has been established at the Regional Office, Nagpur.

 

 

 

 

Regional Chemical Laboratory

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The Regional Chemical Laboratory of the CGWB, CR is located in Nagpur and is well equipped with qualified technical staff to undertake the analysis of ground water, surface water and effluents samples for various parameters. Under the World Bank assisted Hydrology Project, the laboratory has been upgraded to level II+ indicating that the laboratory is capable of carrying out the analysis of water samples for heavy metals, major ions in water, pollution related parameters (COD, BOD) and bacteriological parameters. Presently, the laboratory is analyzing nearly 2500 water samples per annum received under different ground water quality related studies undertaken by the Board. These samples are analyzed for the various parameters depending on the objective of study. The laboratory takes utmost care to keep the highest possible standard of water quality data generated through it. The validation of the data through standard checks is carried out before reporting the data. The laboratory also participates in various Analytical Quality Control Exercises(AQC) undertaken by the recognized laboratories and also undertakes within laboratory AQC exercises.

 

 

 

 

 

Ground Water Quality Monitoring

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The CGWB, CR, Nagpur is monitoring the ground water quality of Maharashtra State and the Union Territory of Dadra and Nagar Haveli (DNH) through a network of above 1500 stations which mainly consist of dugwells lying in shallow zone. These stations are monitored four times in a year in the month of January, May, August and November. The sampling of ground water is carried out in the month of May (pre-monsoon) for analysis of nearly 15 parameters, which include mainly the major ions and harmful elements dissolved in ground water.

 

 

 

 

 

Ground Water Quality Scenario in Maharashtra

 

 

 

 

The ground water quality monitoring carried out by the board in Maharashtra State and the Union Territory of Dadra and Nagar Haveli in the year 2004-05 through its monitoring wells indicates that the ground water quality is good in major parts of the state and union territory (fig.1) and is dominated by the alkaline earth-weak acid (Ca - HCO3) type of water (fig.2). The total dissolved solids (TDS) in 54.3% of ground water samples collected during ground water monitoring was below desirable limit (500 mg/L) and 43.3% of samples show the TDS concentration between the desirable and maximum permissible limit of BIS drinking water standards indicating that the ground water in the state is suitable for drinking purpose (fig.3). The SAR values of 98.77% of samples were found between 0 - 10 which show that the water is good for irrigation purpose. However, classification of the samples as per salinity and sodium hazard (U.S. Salinity diagram) shows that majority of ground water samples fall in medium salinity & low sodium and high salinity & low sodium hazard zone (Table).

 

 

 

 

 

Although, the results of ground water quality monitoring study and specific studies carried out by the board have shown that the ground water quality in some urban and industrial pockets of Maharashtra State is undergoing deterioration especially in the areas where chemical and sugar industries are located. The concentration of few toxic ions and load of organic matter in ground water in the vicinity of these industries are increasing. The contamination of ground water with nitrate due to lack of proper sanitation facilities, disposal of domestic waste and sewage in unlined channels and agricultural activities in rural and urban parts of the state is becoming a common phenomenon. The natural contamination of ground water with fluoride in Yavatmal, Chandrapur, Bhandara, Nanded, Osmanabad and Nagpur district is also becoming common. The inland salinity problem in Purna basin of Amravati, Akola and Buldhana districts is making ground water management difficult. A few cases of seawater ingression in coastal districts of the State have also come into highlight during the monitoring.

 

 

 

 

 

Recently, the board has carried out the ground water quality monitoring for arsenic in the State and the Union Territory. The results of the study indicates that the concentration of arsenic in the ground water of the monitoring wells (shallow aquifer) of State and the Union Territory is 10 times lower than the maximum permissible limit of BIS drinking water standards for arsenic (0.01 mg/L).

 

 

 

 

 

Distribution of Total Dissolved Solids in Ground Water in Maharashtra State and the Union Territory of Dadra and Nagar Haveli (2004):

 

 

 

 

 

 

  Classification of Type of Ground Water in Maharashtra State and the Union Territory of Dadra and Nagar Haveli (2004)

Suitability of Ground Water in Maharashtra State and the Union Territory of Dadra and Nagar Haveli for Drinking Purposes.

 

 

 

 

 

 

 

 

Classification of Ground Water in Monitoring Wells of Maharashtra and the Union Territory of Dadra and Nagar Haveli for Irrigation Purposes:

 

 

EC (mS/cm)

(Salinity hazard)

NO. OF SAMPLES

SAR (Sodium hazard)

<10 (low)

10 – 18(medium)

18 – 26(high)

>26 (Very high)

<250 (low)

81

81

-

-

-

250 – 750 (medium)

245

245

-

-

-

750 – 2250 (high)

428

427

1

-

-

2250 – 5000 (very High)

50

43

6

1

-

>5000

7

5

1

-

1

Total

811

801

8

1

1

 

 

 

 

 

Ground Water Contamination

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The contamination of ground water from the manmade and natural sources is causing a great threat to the ground water system. The increase in urbanization and industrialization are generating huge quantity of waste and wastewater. The disposal of these waste and wastewater without proper treatment on unlined surface is finding its way to groundwater through percolation. The increase in use of chemical fertilizers, insecticide and pesticide in agricultural field has also contaminated the ground water. In coastal area, the increase in demand of water has led to excessive abstraction of ground water due to which the problems like sea water intrusion is arising. The excessive abstraction of ground water and dewatering in mining areas has also caused changes in geo-chemical environment leading to appearance of hazardous metals like Arsenic in ground water. The contamination of groundwater due to release of elements like fluoride from its naturally occurring minerals is also becoming cause of concern. The absence of regular recharging of ground water and increase in evapotranspiration rate under natural conditions have given rise to inland salinity problems. These contaminations of ground water from anthropogenic and natural sources have led to  the undesirable change in the physical, chemical and bacteriological quality of ground water making it unsuitable for the drinking, irrigation and industrial use.

 

 

 

 

 

The Central Ground Water Board, Central Region, Nagpur has undertaken specific ground water pollution studies in different parts of Maharashtra to study the impact of natural and manmade activities on the ground water quality. The results of these studies are summarized under Ground Water Pollution studies.

 

 

 

 

 

 

 

 

Water Quality and Human Health

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The water quality and human health are closely related. The water causes 75% of diseases to the human beings. It is estimated by World Health Organization (WHO) that the 2000 million people in the developing world do not have access to safe drinking water, which is the cause of spreading of water borne diseases. The concentrations of the several inorganic and organic substances dissolved in water beyond acceptable range may cause an adverse impact on human health. The harmful effects on human body depending on the quality of water are summarized below.

 

Effect of water quality on human health

 

 

PARAMETERS

PROBABLE EFFECTS

 Colour

Makes water aesthetically undesirable.

 

 Odour

Makes water aesthetically undesirable.

 

 Taste

Makes water aesthetically undesirable.

 

 Turbidity

High turbidity increases contamination/pollution

 

 pH

Indicative of acidic or alkaline waters, affects taste and corrode water supply system

 

 Hardness

Affects water supply system (scaling), excessive soap consumption, calcification of arteries, may cause             

urinary concretions, diseases of kidney or bladder and stomach disorder.

 

 Iron (Fe)

Gives bittersweet astringent taste causes staining of laundry and porcelain. In traces it is essential for 

nutrition.

 

 Chloride (Cl)

May be injurious to some people suffering from diseases of hearts and kidneys. Taste, indigestion, corrosion and palatability are affected.

 Residual free 

 Chlorine,

Excessive free chlorine in drinking water may cause asthma, colitis and eczema. (Only when water is chlorinated)

 

 Total Dissolved

 Solids (TDS)

Palatability decreases and may cause gastro-intestinal irritation in human, may have laxative effect particularly upon transits.

 

 Calcium (Ca)

Insufficiency causes severe rickets; excess causes concretions in the body such as kidney or bladder stones and irritation in urinary passages. Essential for nervous and muscular system, cardiac functions and in coagulation of blood.

 

 Magnesium (Mg)

Its salts are cathartic and diuretic. High concentration may cause laxative effect particularly on new users. Mg deficiency is associated with structural and functional changes. It is essential as an activator of many enzyme systems.

 

 Copper (Cu)

Astringent taste but essential element in human metabolism. Deficiency results in nutritional anemia in infants. Large amount may result in liver damage, cause CNS irritation and depression. In water supply system, it enhances corrosion of aluminum particular.

 

 Sulphate (SO4)

Causes gastro intestinal irritation with Mg or Na can have a cathartic effect on users. Conc. more than 750 mg/L along with Mg may have laxative effect.

 

 Nitrate (NO3)

Causes infant methaemoglobinaemia (Blue Babies) at very high conc., causes gastric cancer and adversely affects CNS and cardiovascular system.

 

 Flouride (F)

Reduces dental carries, very high concentration may cause crippling skeletal fluorosis. Less than 1.0 mg/L is essential.

 

 Cadmium (Cd)

Acute toxicity may be associated with renal, arterial hypertension, itai-itai disease. Cd salts cause cramps, nausea, vomiting and diarrhea.

 

 Lead (Pb)

Toxic in acute and chronic exposures, burning in mouth, severe inflammation of gastro-intestinal tract with vomiting and diarrhea, chronic toxicity produces nausea, severe abdominal pain, paralysis, mental confusion, visual disturbances, anemia etc.

 

 Zinc (Zn)

An essential element in human metabolism. Taste threshold for Zn occurs at about 5 mg/L, imparts astringent taste to water.

 

 Chromium (Cr)

Hexavalent state of Cr produces lung tumors, can produce coetaneous and nasal mucous membrane ulcers and dermatitis.

 

 Arsenic (As)

Causes skin damage, circulatory problems and risk of skin cancer.

 

 Antimony (Sb)

Increase in blood cholestorel, decrease in blood sugar.

 

 Aluminum (Al)

Leads to neurological disorders.

 

 Barium (Ba)

Increases blood pressure.

 

 Beryllium (Be)

Is carcinogenic (cancerous).

 

 Cyanide (CN)

Causes nerve damage, thyroid problem.

 

 Mercury (Hg)

Neurological and renal disturbances. Excess causes gonad toxic and mutagenic effects and disturbs the cholesterol metabolism.

 

 Manganese (Mn)

Essential as a cofactor in enzyme systems and metabolism processes. Excess causes change in appetite and reduction in metabolism of iron to form hemoglobin. Imparts undesirable taste and stains plumbing fixtures and laundry.

 

 Selenium (Se)

Leads to hair, finger loss, numbness in fingers or toes, circulatory problems.

 

 Boron (B)

Affects CNS, may cause nausea, cramps, convulsions, coma, etc.

 

 Alkalinity

Imparts unpleasant taste, may be deleterious to humans in presence of high pH, hardness & TDS.

 

 Pesticides

Imparts toxicity when it accumulates in organs of human body affecting immune and nervous systems. May be carcinogenic.

 

 Phosphate (PO4)

High conc. may cause vomiting and diarrhea, stimulate secondary hyperthyroidism and bone loss.

 

 Sodium (Na)

Harmful to persons suffering from cardiac, renal and circulatory diseases.

 

 Potassium (K)

An essential nutritional element but in excess is laxative.

 

 Nickel (Ni)

Non toxic element but may be carcinogenic (cancerous), can react with DNA resulting in DNA damage.

 

 Pathogenic Micro-

 Organisms

Causes water born diseases like Jaundice, Typhoid, Cholera etc. produces infections involving skin, mucous membrane of eyes, ears and throat.

 

 Radioactive

 Materials

   Increases risk of cancer

 

 

 

 

 

 

Water Quality Standards

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Depending on the impact of various constituents of water on human health crops and industrial processes, certain standards have been laid down by the different standard institutions like Bureau of Indian Standards (BIS), Indian Council of Medical Research (ICMR), World Health Organisation (WHO) and Food and Agriculture Organization (FAO) of United Nations for deciding the suitability of water for drinking and irrigation use. These standards are summarized in the following tables.

 

 

 

 

 

1. BIS Drinking Water Standards (IS 10500 – 91,Revised 2003)

 

 

SR.NO.

PARAMETERS

DESIRABLE LIMIT